Acceleration of nucleophilic CH activation by strongly basic solvents.
نویسندگان
چکیده
(IPI)Ru(II)(OH)(n)(H(2)O)(m), 2, where IPI is the NNN-pincer ligand, 2,6-diimidizoylpyridine, is shown to catalyze H/D exchange between hydrocarbons and strongly basic solvents at higher rates than in the case of the solvent alone. Significantly, catalysis by 2 is accelerated rather than inhibited by increasing solvent basicity. The evidence is consistent with the reaction proceeding by base modulated nucleophilic CH activation.
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ورودعنوان ژورنال:
- Journal of the American Chemical Society
دوره 132 36 شماره
صفحات -
تاریخ انتشار 2010